• 专利附录
  • 专利说明
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    • 专利摘要:
    Method for filling or withdrawing a tank (1) of gas under pressure, in particular of fuel such as hydrogen gas, the tank being delimited by a wall of generally cylindrical shape having determined thermo-physical dimensions and properties and known, the method comprising a regulation of the flow rate of the gas introduced or, respectively of the withdrawn gas, and / or the temperature of said introduced gas, to prevent the tank from reaching a determined high temperature threshold or a low threshold determined temperature, the method being characterized in that it comprises a step of estimation in real time by calculation of at least one tank temperature among: the average temperature of the tank wall Twall, average (r, t) as a function of time (t), the maximum temperature reached by the Twall tank wall, max (t) as a function of time, the minimum temperature reached by the wall of the Twall tank, m in (t) as a function of time and in that the regulation of the flow rate of the gas flow or the temperature of the said gas is carried out as a function of the said calculated reservoir temperature.
    公开号:FR3036159A1
    申请号:FR1554207
    申请日:2015-05-12
    公开日:2016-11-18
    发明作者:Thomas Bourgeois；Fouad Ammouri；Mathilde Weber；Elena Vyazmina
    申请人:Air Liquide SA；LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude；
    IPC主号:
    专利说明:

    [0001] The present invention relates to a method for filling or withdrawing a pressurized gas tank. The invention also relates to a method for filling or withdrawing a pressurized gas tank, in particular a fuel such as hydrogen gas, the tank being delimited by a wall of generally cylindrical shape having dimensions and thermal properties. -physical determined and known, the method comprising a regulation of the flow rate of the introduced gas flow or, respectively of the withdrawn gas, and / or the temperature of said introduced gas, to prevent the tank from reaching a determined high temperature threshold or a low threshold of temperature. The invention relates in particular to the filling or withdrawal of hydrogen tanks under pressure, in particular composite tanks storing gas at high pressures, in particular 200bar, 700bar or 1000bar. These composite tanks (especially type IV) have a more extreme temperature resistance than metal tanks. For example, the operating temperature limits for such tanks should be between -40 ° C and + 85 ° C. Thus, the filling processes (producing a heating) and the racking process (producing cooling) must be controlled.
    [0002] This control can be achieved in particular by controlling the gas flow rate and / or its temperature. A motor vehicle filling standard (SAE) has been developed to establish cooling recommendations and filling rates according to initial conditions (ambient temperature, initial pressure in the tank, etc.). This model is based on the temperature of the gas in the tank and not the temperature of the tank (which is generally lower than that of the gas). The measurement of the maximum temperature reached by the reservoir is however difficult to measure.
    [0003] Under these conditions, the recommendations of the filling conditions established by this standard are considered too restrictive and therefore partly unnecessary and generating significant additional costs.
    [0004] An object of the present invention is to overcome all or part of the disadvantages of the prior art noted above. To this end, the method according to the invention, which moreover conforms to the generic definition given in the preamble above, is essentially characterized in that it comprises a step of real-time estimation by calculation of at least one reservoir temperature among: the average temperature of the Twall tank wall, average (r, t) as a function of time (t), the maximum temperature reached by the wall of the Twall tank, max (t) as a function of time, the minimum temperature reached by the wall of the tank Twall, min (t) as a function of time and in that, the regulation of the flow rate of the gas flow or the temperature of said gas is carried out according to said tank temperature calculated. According to the invention it is thus possible to estimate, via a mathematical model based on measurements of pressure in the tank and the ambient temperature, the maximum or minimum temperature reached by the wall of the tank.
    [0005] The gas pressure and ambient temperature values are measured external data. That is, no complex measurements are required in the filled or withdrawn tank. A three-dimensional dynamic mathematical model can be used to calculate the temperature in the tank, including its wall.
    [0006] However, preferably the invention uses a simplified model. This simplified model can be based in particular on the input data such as: the temperature of the gas in the transfer line to the tank, its pressure, the geometric characteristics of the tank, the ambient temperature. Other thermo-physical parameters of the reservoir can be used such as thermal conductivity, heat capacity and density. As illustrated in FIG. 3, the initial mass m (0) of gas in the tank 1 can also a known or estimated input data. Similarly for the flow rate Q (t) of gas transferred at time t.
    [0007] Preferably, the model calculates on this basis and in real time the average temperature of the gas in the tank and its state of filling ("SOC = filling percentage in which 100% corresponds to the mass quantity of gas of the tank filled at its operating pressure and a determined homogeneous temperature, especially 15 ° C). This state of charge SOC is directly related to the average temperature of the gas in the tank and its pressure via a gas state equation. Preferably, the model calculates on this basis in real time also the mean temperature of the tank wall in two dimensions Tw, average (r, t) in which r is the spatial coordinate (in particular the radius r with respect to the central longitudinal axis of the cylindrical tank) and t the time. Preferably, the model calculates on this basis in real time also the maximum temperature of the tank wall Tw, max (t) in which t is the time. The model can also calculate the minimum tank wall temperature Tw, min (t) as a function of time t. These data can be obtained if necessary from the temperature Tgas, average (t) of the gas (calculated). This mathematical and thermodynamic model can be integrated with a programmable logic controller ("PLC") making it possible to estimate in real time the extreme temperature during filling or racking. The average temperature of the gas in the tank can also be calculated. From this extreme temperature data of the wall, the controller can adjust the gas transfer rate (filling or withdrawal) and / or the gas cooling level (filling) to remain in the safety temperatures. This solution makes it possible to avoid flow regulation or oversized cooling compared to the real need. According to other possible features: - during a filling, when the calculated tank temperature reaches a high threshold (SH) determined, the flow and in particular the gas flow is decreased and / or the temperature of the gas supplied to the reservoir is reduced by heat exchange with a source of cold, - during a filling, when the calculated reservoir temperature is lower than the high threshold of a determined value, the gas flow and in particular its flow is increased and / or the temperature of said gas and / or tank is increased by heat exchange with a heat source, the method comprises a step of calculating the Richardson Number (Ri) for the gas in the tank as a function of time, a step of comparing the number of calculated Richardson number with a determined reference value (Vr) of between 0.05 and 1.5 and preferably between 0.05 and 0.15 and, when the number of Richardson number calculated is less than the determined reference value the temperature of the gas in the tank is considered homogeneous, that is to say that the maximum temperature reached by the wall of the tank Twall, max (t) as a function of time is equal to the average temperature of the wall of the Twall tank, average (r, t) in contact with the gas as a function of the time (t): Twall, max (t) = Twall, average (r = r_liner, t). when the number of Richardson number calculated is greater than the determined reference value, the temperature of the gas in the reservoir is considered heterogeneous, that is to say that the maximum temperature reached by the wall of the Twall reservoir, max (t) as a function of time is not equal to the average temperature of the wall of the tank in contact with the gas as a function of time (t), ie at the level of what forms the "liner" of the tank , Twall, average (r = reservoir liner radius, t), and in these conditions, the method includes a step of increasing the gas flow rate supplied to the reservoir to decrease the value of Richardson's number calculated below the reference value (Vr) determined and thus make the gas homogeneous in temperature, - during a filling, when the Richardson number is greater than the reference value, the flow of gas and in particular its flow is increased, - the process comprises, before r filling or, respectively, before withdrawal, a step of determination or detection by sensor (s), of the initial temperature T (0) of the gas in the tank, of the initial pressure P (0) of the gas in the tank, the initial average temperature of the tank wall Tw, average (0) and a step of determining the initial mass of gas in the tank m (0) then, during a filling when the number of Richardson number calculated is If the reference gas temperature is lower than the reference value, the temperature of the gas in the tank is considered homogeneous, ie the maximum temperature reached by the wall of the Twall tank, max (t) as a function of time is equal to the temperature. average of the wall of the tank Twall, average (r = r = radius of the tank liner, t) in contact with the gas in function 3036159 5 of the time (t), and under these conditions, the method comprises, during filling , a step of calculating the temperature Tgas, average (t) of the gas in the reservoir in real time as a function of the time and the mean temperature of the wall Twall, average (r, t) in real time as a function of time (t) from a balance sheet mass and enthalpy applied to the gas in the tank and also from an energy balance in the tank wall, the gas state equation (notably the equation of the real gases), and a balance of the heat exchange between the gas and the wall, and between the wall of the tank is the outside, - the method comprises, before filling or, respectively, before withdrawal, a step of determination or detection by sensor (s), the initial temperature T (0) of the gas in the tank, the initial pressure P (0) of the gas in the tank, the initial average temperature of the tank wall Tw, average (0) and a step of determining the the initial mass of gas in the reservoir m (0) then, when filling when the number of The calculated Richardson's temperature is higher than the determined reference value. The temperature of the gas in the tank is considered heterogeneous, ie the maximum temperature reached by the wall of the Twall tank, max (t) as a function of time. is not equal to the average temperature of the wall of the Twall tank, average (r) = r_liner, t) in contact with the gas as a function of time (t), and under these conditions, the process comprises, during filling , a step of calculating the temperature Tgas, average (t) average of the gas in the real-time reservoir as a function of time (t) and the average temperature of the wall Twall, average (r, t) in real time in time function from a mass and enthalpy balance applied to the gas in the reservoir and from an energy balance in the tank wall, from the gas state equation (perfect gas equation or actual), and a balance of heat exchange between the tank wall is the ex and in that the method comprises a step of calculating the maximum temperature reached by the Twall tank wall, max (t) as a function of time, this maximum temperature reached by the wall of the Twall tank, max (t) depending The time being obtained by correlation from the temperature Tgas, average (t) of the gas in the reservoir calculated in real time as a function of time and as a function of the average temperature of the wall Twall, average (r, t) in real time as a function of time (t), the process comprises a step of calculating the enthalpy hin (t) of the gas entering or leaving the reservoir as a function of time, a step of measuring or calculating the mass of gas m (t) introduced or withdrawn from the tank as a function of time or, respectively, a step of determining the pressure P (t) in the tank as a function of time, the method comprising a step of determining the temperature average gas Tgas, avera ge (t) at time t in the reservoir in degree K, this average temperature Tgas, average (t) being expressed as a function of the first degree of the average temperature of the gas T (t-1) at the previous instant (t-1) and a convective heat exchange coefficient 10 between the gas and the inner wall of the tank (1) at time (t-1) in Wm-2.K1, wherein the coefficient of heat exchange kg (t-1) is given by the relation kg = (Ag / Dint) .Nuint in which Ag is the thermal conductivity of the gas in the tank in Wm-1.K1, Dint is the internal diameter of the tank (1 ) in meters and NuDint the Nusselt number of the gas in the tank (1) (dimensionless), and in which the Nusselt number of the gas is expressed as a function of the Reynolds number (Redin) (dimensionless) relative to the forced convection in the tank and Rayleigh number (RaDint) (dimensionless) relative to the internal natural convection in the tank according to a formula NuDint = a.RaDint b + c.Redind in which a and c are dimensionless coefficients as a function of the ratio (Lint / Dint) between the internal length of the reservoir Lint in meters and the internal diameter of the reservoir Dint in meters and the ratio (Dint / di) between the internal diameter of the reservoir Dint in meters and the diameter of the injector di in meters, a, b, c and d being positive real numbers without dimension, a being between 0 and 1, b being between 0.2 and 0.5, c being between 0 and 1 and d being between 0.5 and 0.9, the method comprises a step of estimating the maximum temperature reached in the thickness of the Twall tank, max (t) depending of time, or respectively the minimum temperature reached in the thickness of the Twall tank, min (t) as a function of time, from the temperature Tgas, average (t) average of the gas in the reservoir calculated in real time according to time (t), said maximum or minimum temperature being obtained from correspondence table (s) obtained by experiments, and / or from calculation and / or simulations so that at a temperature Tgas, average (t) of the gas 3036159 7 in the reservoir calculated in real time as a function of time (t) corresponds, according to the known conditions of gas flow, the gas injector diameter in the reservoir and the dimensions and characteristics of the reservoir, a maximum or, respectively, minimum temperature in the thickness of the reservoir as a function of time, - the Richardson Number (Ri) for the gas in the reservoir as a function of time is calculated from the Grashoff (Gr) number for the gas and the Reynolds number (Re) for the gas at time (t) according to the following formula: Ri = Gr / Re2, in which the Grashof (Gr) and Reynolds (Re) numbers are known or calculated data from the pressure value of the gas measured or the mass of gas in the tank and the temperature gas Tgas, average (t) average of the gas in the tank, - during a withdrawal, when the calculated tank temperature reaches a determined low threshold, the gas flow is decreased, - the method comprises a measurement step or continuously calculating at least one of: the pressure Pin (t) at the time (t) of the gas introduced into or withdrawn from the tank, the temperature Tin (t) at the time (t) of the gas introduced into or withdrawn of the tank, the P (t) pressure in the tank at time (t), the ambient temperature (Tamb (t) at time (t), the mass of gas m (t) in the tank at time (t), 20 the process is carried out by a hydrogen gas tank filling station comprising at least one high-pressure hydrogen source, at least one transfer line selectively connecting the source to a reservoir, and an electronic device acquisition, storage and processing of data such as a computer or microprocessor, said body pilo both the transfer of gas between the source and the reservoir, the logic (4) being programmed to calculate in real time at least one tank temperature among: the average temperature of the tank wall Twall, average (r, t) as a function of time (t), the maximum temperature reached in the thickness of the Twall tank, max (t) as a function of time, the minimum temperature reached in the thickness of the Twall tank, min (t) as a function of time and to regulate the flow rate of the gas flow and / or the temperature of said gas as a function of said calculated tank temperature, 3036159 8 - during a withdrawal, when the calculated reservoir temperature is higher than the low threshold (SB), the gas flow is increased, the initial temperature T (0) of the gas in the tank, and the initial average temperature of the wall of the tank T, (0) are approximated to be equal to the ambient temperature measured or indicated before filled ssage, - the geometric dimensions of the tank are known, for example communicated before filling in particular: the internal length (Lint) of the tank, the internal diameter (Dint) of the tank, - the diameter (di) of the injector meter is also a known parameter before filling, the initial mass of gas m (0) in the tank (in kg) is calculated by a gas state equation from the known initial pressure values P (0) (in Pa) and of initial temperature T (0) of the gas (in K), - in the case of withdrawal, the NuDint number of Nusselt (dimensionless) of the gas in the tank (1) is given by the formula NuDint = a.RaDintb '- the determined and known thermo-physical properties of the reservoir comprise at least one of: the density, the specific heat capacity, the thermal conductivity of the inner shell of the tank (liner), the density, the specific heat capacity, thermal conductivity 20 of the composite, the tank volume, the internal and external lengths and diameters of the tanks, the thickness of the liner and composite, the inner and outer surface of the tank, the total mass of the liner, the total mass of the composite, the nozzle diameter in the tank, the coefficient of pressure drop at the inlet of the bottle, the emissivity of the external surface of the tank, 25 - the temperature Tgas, average (t) mean of the gas in the tank is the average temperature for the storage volume of the tank (in K), - the tank is generally cylindrical, the average temperature of the wall of the tank Twall, average (r, t) according to a space variable (r ) and time (t), is the temperature in the wall thickness of the tank in a direction transverse to the wall, the space variable (r) being the position in the thickness of the wall in one direction parallel to a cylinder radius from the axis l central longitudinal axis of the cylinder (in m), 3036 159 9 - the maximum temperature reached in the thickness of the tank Twall, max (t) as a function of time is the maximum temperature (in K) reached by the wall at the time (t) regardless of the portion of the wall, that is to say a maximum temperature in the spatial sense of the term, the initial temperature T (0) of the gas in the tank is measured by a temperature sensor, for example an ambient temperature sensor, - the initial pressure P (0) of the gas in the tank (in Pa) is measured by a pressure sensor at the inlet or in the tank, - the initial average temperature of the tank wall T (0) (in K) is measured by a temperature sensor or is approximated to the initial gas temperature in the tank T (0), - the determination of the initial gas mass in the tank m (0) is calculated using the ideal or real gas equation from the following known data: initial concentration P (0) of the gas in the tank, the volume V of the tank, the initial temperature of the gas in the tank T (0) and the compressibility factor Z of the real gas (dimensionless) or the constant R of the ideal gases, the high temperature threshold (SH) is between 65 and 105 ° C and preferably equal to 85 ° C, the gas flow is reduced during filling by reducing the rate of increase of pressure in the tank, - the low temperature threshold is between -50 ° C and -30 ° C and preferably equal to -40 ° C, - the temperature and pressure of the gas in the tank are considered homogeneous in the estimates or calculations, - the filling speed is controlled by means of an integral proportional type valve or pressure regulator, - the tank is a composite tank type IV or III, - the wall of the composite tank comprises a plastic liner or metal 30 and a layer of composite material te, - the average gas temperature Tgas, average (t) is determined in real time by the numerical resolution of two enthalpic balances: a first enthalpy balance applied to the gas injected into the reservoir and a second enthalpic balance sheet applied to the wall the tank; the numerical resolution of the equation of heat in the wall, using the real gas state equation applied to the gas in the reservoir, the thermophysical properties of the gas such as the compressibility factor Z, the specific heat capacity cp and the mass enthalpy of the gas being known, - the average temperature (average in two-dimensional 2D) of the tank wall Tw (r, t) is determined in real time by the numerical resolution of two enthalpic balances: a first enthalpy balance applied to the gas injected into the reservoir and a second enthalpy balance applied to the tank wall; the numerical resolution of the equation of heat in the wall; using the real gas state equation applied to the gas in the reservoir, the thermophysical properties of the gas such as the compressibility factor Z, the specific heat capacity Cp and the mass enthalpy h of the gas being known, - the number Richardson (dimensionless) is calculated as the ratio between Grashoff number (dimensionless) and Reynolds number (dimensionless) squared, - the Reynolds number can be equal to the Reynolds number of the input gas. reservoir (input density that multiplies the input speed multiplies the diameter of 1 "gas injector and divided by the dynamic viscosity at the inlet), - the Reynolds number can be equal to the Reynolds number at the bottom of the the bottle (density of the gas in the bottle that multiplies the speed of the gas at the bottom of the bottle that multiplies the diameter of the bottle and divided by the dynamic viscosity of the gas, 25 - the speed at the bottom of the bottle eille (in ms-1) can be calculated from the velocity of the cylinder inlet gas (ve), the injector diameter (di) (in meters), the internal length of the bottle ( Lint) (in meter) via the following formula: vf = (ve.6,2.di) / Lint - the Grashof Gr number can be calculated by the formula: gas acceleration constant 30 * isobaric coefficient of thermal expansion * (T (t) - Tw (r = rininer, t)) * (Dint) 3 / (kinematic viscosity of the gas) 2, 3036159 11 - the tank has a ratio (Lint / Dint) between the internal length of the tank Lint in meters and the internal diameter of the reservoir Dint in meter between 1 and 7 and preferably between 1.8 and 6.6, and preferably less than 4.5, - the ratio (Dint / di) between the internal diameter of the reservoir Dint in meter and the diameter di of the injector in meter is between 30 and 100 and preferably between 35.0 and 72.3, - the Reynolds number (Red) (dimensionless) relative to theforced convection in the reservoir is between 5.6 × 10 -4 and 2.0 × 10 6 - the number of Rayleigh (Radint) (dimensionless) relative to the internal natural convection in the tank (1) is between 8.0 × 10 8 and 1.0 × 10 12 the mass mt (t) of gas in the tank is calculated in real time via the gas state equation (equation of the real gases preferably) from the average temperature value of the gas Tgas, average (t) in the calculated reservoir (1) and the pressure P (t) of the gas in the reservoir measured in real time. The invention may also relate to a device for filling or withdrawing gas from a reservoir comprising a transfer line comprising a valve and connectable to a reservoir, the device comprising an electronic device for acquiring, storing and processing data such as a computer or microprocessor, said member controlling the transfer of gas between the source and the reservoir, the logic Electroni that being programmed to calculate at least one tank temperature among: the average temperature of the tank wall Twall, average (r, t) according to its thickness (radius r) and as a function of time (t), the maximum temperature reached in the thickness of the tank Twall, max (t) as a function of time, the minimum temperature reached in the thickness of the tank Twall, min (t) as a function of time and to regulate the flow rate of the gas flow as a function of said temperature of the current reservoir calculated. The invention may also relate to any alternative device or method comprising any combination of the above or below features. Other particularities and advantages will appear on reading the following description, made with reference to the figures in which: FIG. 1 represents a schematic and partial view illustrating an example of a tank filling installation that can be used to FIGS. 2 to 6 diagrammatically and partially illustrate various logigrams illustrating examples of steps that can be implemented by the method according to the invention. Figure 1 schematically illustrates a filling station (or withdrawal) of a tank 1 of pressurized gas, including fuel such as hydrogen gas.
    [0008] The tank 1, for example a type IV composite tank, is delimited by a wall 1 of generally cylindrical shape having determined and known dimensions and thermophysical properties. The station may comprise at least one source of high-pressure hydrogen, at least one transfer line 2 selectively connecting the source 1 to the tank 1 and an electronic member 4 for acquiring, storing and processing data such that a computer or microprocessor. The electronic member 4 controls the transfer of gas between the source 10 and the tank 1 and can be programmed to calculate in real time at least one tank temperature (1) among: the average temperature of the tank wall Twall, average (r, t) as a function of time (t), the maximum temperature reached in the thickness of the Twall tank, max (t) as a function of time, the minimum temperature reached in the thickness of the Twall tank, min (t) as a function of time and to regulate the flow rate of the gas flow and / or the temperature of said gas as a function of said calculated reservoir temperature (see FIG. 3).
    [0009] Of course, conventionally, in addition to controlling the extreme temperature reached by the tank wall (minimum and / or maximum), the mass of gas in the tank is preferably also controlled (or any other parameter reflecting the amount of gas). in the tank). This mass of gas can be calculated conventionally from the calculated gas temperature and the measured gas pressure. The known input parameters for this or these estimation calculations include, for example: the thermodynamic properties of the gas (of the reservoir, in particular of its liner and composite structure), the GE geometry of the reservoir (length, diameter,. ..). These data are known constants. the known conditions of pressure P (0), temperature T (0) and temperature of the wall Twall (0) at the initial moment t = 0. These conditions can be measured or determined or approximated, - the real-time conditions of the incoming gas pressure at time t Pin (t), the temperature of the incoming gas Tin (t) at time t, the pressure of the gas in the tank P (t) at time t (measured for example in the line connected to the inlet / outlet of tank 1), the ambient temperature Tamb (t) at time t. coefficients a, b, c, d of heat exchange and correlation (explained below). The coefficients a, b, c, d can be obtained by experimental tests for each type of tank from tests of rise and pressure drop in the tank. These coefficients may, if necessary, be correlated with dimensions or dimension ratios of the reservoir. From these known input data, the electronic member 4 can be configured to calculate in real time the following output data: the average temperature of the gas in the tank T (t) = Tgas, average (t) at time t as a function of time t, - the mass m (t) of gas in the tank at the time, - the mean temperature of the tank wall Twall, average (r, t) as a function of time t, r being the radius coordinate from the longitudinal axis of the tank, 25 - the maximum temperature reached by the Twall tank wall, max (t) as a function of time, - the Richardson Ri number (t) for the gas in the tank at time t (see below). The mean temperature of the wall of the Twall tank, average (r, t) is the average in two dimensions (2D), i.e. it represents the temperature of the wall layer at the coordinate r taken from the longitudinal axis of the tank. This temperature is homogeneous in two dimensions but may vary depending on the radius r. This average temperature is calculated by solving for example the equation of heat in the wall. The maximum (respectively minimum) temperature reached by the wall of the Twall tank, max (t) as a function of time can be the temperature of the wall 5 at the time t at the interface between the gas and the wall. Hereinafter will be described an example of use of such a model for a filling station. Suppose a filling performed at a constant inlet gas temperature. At each time interval, the model (implemented by the electronic device 4 which controls the filling / withdrawal) estimates in real time the maximum temperature reached by the Twall tank wall, max (t) as a function of time. If this maximum temperature becomes close to the allowable limit (85 ° C. for example), in this case the control member 4 can reduce the rise in pressure by acting for example on the control valve 3. This decrease in the pressure ramp (pressure increase per unit of time) reduces or suppresses the increase in temperature. If the maximum temperature is below the allowable value, the pressure increase rate can be increased.
    [0010] It is therefore a method of controlling the filling rate as a function of the maximum temperature of the tank wall estimated / calculated. An example of an application is illustrated schematically in FIG. 5. Thus, from the input parameters (steps 11, 12, 13, 14, 15) the average gas temperatures Tgas, average (t) as a function of time t and the maximum temperature reached by the Twall tank wall, max (t) as a function of time are calculated (step 16). On this basis, the SOC state of charge is calculated (step 17) and then this state of charge is compared with the target state of charge (100%). If the target state of charge is reached the filling is interrupted (step 19) otherwise it is continued and the maximum temperature of the tank Twall, max (t) is compared with the threshold limit 85 ° C (minus a safety factor TS) cf. step 20. If this temperature remains within the allowable limits (step 21) the filling rate can be maintained or increased and the process returns to the step of measuring the pressure of (step 15). If this temperature is not within the allowable limits (step 22), the filling rate can be reduced and the process returns to the step of measuring the pressure P (t) of (step 15). Alternatively or cumulatively to the flow control, the temperature of the gas can be controlled (the gas is cooled or its cooling is increased if the maximum temperature approaches the allowable limit). Such an example is illustrated in FIG. 6. The process of FIG. 6 differs from that of FIG. 5 only in that, at the end of step 17 of calculating the state of charge SOC, the process comprises a step 27 during which the Richardson Ri number of the gas is compared with a reference value Vr (here Vr = 1). If the number of Richardson R1 exceeds the reference value ("Y," step 21) the filling rate can be maintained or increased and the process returns to step 16 of calculating the average gas temperature Tgas, average in function of the time t and the maximum temperature reached by the Twall tank wall, max (t) as a function of time. If the Richardson number Ri is less than the reference value ("N", step 21) the maximum temperature of the Twall reservoir, max (t) is compared with the threshold threshold (minus a safety factor TS) cf. Step 20. Depending on whether this maximum temperature of the Twall tank, max (t) reaches the limit threshold (minus a safety factor TS ("Y step 122), a new inlet gas temperature is calculated (ie that is, the temperature of the filling gas is lowered.) The process returns to step 11 in which the temperature of the gas Tin (t) is supplied to the model, if on the other hand this maximum temperature of the tank Twall, max (t ) remains below the limit threshold (minus a safety factor TS ("step 121), a new inlet gas temperature is calculated (i.e., the temperature of the fill gas is increased). The process returns to step 11 in which the incoming gas temperature Tin (t) is supplied to the model, as illustrated diagrammatically in Figure 2, when filling, when the calculated tank temperature (1) reaches a threshold high (SH) 30 determined, the flow and in particular the flow of gas is decreased and / or the temperature of the gas supplied to the tank (1) is decreased by heat exchange with a source of cold. Similarly, during a withdrawal, when the calculated tank temperature reaches a certain low threshold (SB), the gas flow can be decreased.
    [0011] FIG. 4 illustrates in more detail a possible consideration of the Richardson Ri number. The Richardson Ri number for the gas in the tank 1 as a function of time is calculated. The method comprises a step 27 for comparing the calculated number of Richardson Ri number with a reference value Vr determined between 0.05 and 1.5 and preferably between 0.05 and 0.15 and in particular equal to 0, 1. When the number of Richardson Ri calculated is less than the reference value Vr (step 127) determined, the temperature of the gas in the tank 1 is considered homogeneous, ie the maximum temperature reached by the tank wall. Twall, max (t) as a function of time is considered equal to the mean temperature of the Twall tank wall, average (r, t) in contact with the gas as a function of time (t): Twall, max (t) = Twall, average (r, t), where r is the radius from the longitudinal axis of symmetry of the cylindrical reservoir. At the interface in contact with the gas (i.e., r = radius at what forms the reservoir liner), r = radius of the liner. When the number of calculated Richardson Ri number is greater than the reference value Vr determined, the temperature of the gas in the tank 1 is considered heterogeneous, that is to say that the maximum temperature reached by the wall of the tank Twall, max ( t) as a function of time is not equal to the average temperature of the Twall tank wall, average (r = radius of the liner, t) in contact with the gas as a function of time (t), and under these conditions the method may comprise a step of increasing the flow rate supplied to the tank 1 in order to reduce the value of the Richardson number (Ri) calculated below the determined reference value Vr (step 227, FIG. 4).
    [0012] A non-limiting example of a model for calculating the average gas temperature in the tank Tgas, average (t) and extreme temperature Twall, max (t) (maximum or minimum) of the tank wall will now be described. . Said model can be based on: - a mass and energy balance of the gas in the tank 1, - a gas state equation, correlations with dimensionless coefficients modeling the heat exchanges between the gas and the tank wall, and between the tank wall and the external environment a one-dimensional heat equation in the tank wall, a correlation between the maximum temperature of the tank wall as a function of time and the average temperature gas and wall in contact with the gas as a function of time. This correlation can be obtained by tests and / or simulations. For example, reference may be made to WO2013014346A1 (or the article "Evaluating the temperature inside a tank during a filling with highly pressurized gas", published in 2014, authors: Thomas Bourgeois and al., Seoul (Korea)): Proceedings of the 20th World Hydrogen Energy Conference, 2014. Calculation details of said model will be described below For the sake of simplification, the reservoir is considered to be filled with gas, however, the adaptation of the model to the case of a withdrawal or a stabilization (neither filling nor withdrawal) will be described ap.rès The model combines the mass and energy balance of the gas and the equation of state of the gas.For a filling, the temperature and the The gas entering the tank 1 has an enthalpy h1, and the gas in the tank is considered to exchange heat with the wall via a heat exchange coefficient kg. ga z in the tank is considered to vary directly depending on the incoming gas flow. In this case, dm 25 dt film In the following, the variation of mass as a function of time will be called dm_dt 111 The first energy equation of the model and the enthalpy balance are applied to the open system of the interior of the tank 1 Kinetic energy and gravitational energy variations are neglected. Knowing the volume V of the reservoir, the inner surface Shit of the reservoir and the gas-specific enthalpy, we have the expression: ## EQU1 ## ## EQU1 ## With these assumptions, the variations of the enthalpy are due to three factors: the compression of the gas, the enthalpy entering, and the exchanges of heat with the wall.The second energy equation is the definition of the variation of enthalpy of a real gas: dP dh = cp dT + (1 - 13T) -p (expression 2) By combining the expressions 1 and 2 we obtain an equation describing the evolution of the temperature of the gas in the tank in function of the pressure increase, the wall temperature, the gas flow rate and the enthalpy of the incoming gas dT dP and CP dt = VfIT - kg Si (Twi T) rii (h - h) (expression 3) To complete the model, the following equation of state of a real gas can be used: PV = ri RZ (T, r (expression 4) 15 To estimate the evolution of the gas temperature the system of equations can be discretized by considering that some derivatives can be calculated as variations and that some variables at time t are close to the values at the moment (t-1) preceding. Thermodynamic parameters Cp, p, h and Z can be estimated for each pressure and temperature using NIST standard tables. At this stage two discretizations can be made according to the choice of the input parameters: mass flow Q (t), or pressure of the gas P (t). The term "input parameter" designates a variable that is known either by its measurement (for example the pressure measured in the filling / withdrawal duct) is known because it is indicated in the model (for example a pressure increase of 0.2 bar per minute). second). The following paragraphs concern the discretization of equations in the case of input-mass flow or pressure data. By combining and discretizing the expressions 3 and 4 we obtain: ## EQU1 ## ## EQU00006 ## where mt-i is At-i) with, mt = mt-i + QtAt with,. At this time, by knowing the state at the previous time (t-1), in addition to the rate signal Q (t) at time t, it is possible to determine the temperature of the gas at time t. From the gas state equation, knowing the pressure P at time (t-1) 10 the temperature of the gas T at time t and the mass m (t) at time t, the pressure P (t) at time t can be calculated. With the following notations: VPt-iTt-i (Pt-Pt-1) mt-1A-kg t_iStnewit-i-Tt-i) At (htutt-i ht-i) At 15 B = RZ t_i, P At It is possible to discretize the previous equations to obtain the expression of the temperature T at time t. Here again, by knowing the system at the previous time (t-1) and the pressure value at time t it is possible to calculate the temperature of the gas at the time. t. From the equation_ of state, knowing Tgas, average (t) and P (t) it is possible to calculate the mass of gas in the tank at time t.
    [0013] In the case of a withdrawal, the temperature of the gas in the tank can be calculated. The only difference from the previous equations is that the enthalpy at the inlet is now the enthalpy at the outlet and is considered equal to that of the gas in the tank. Thus the term (hin-h) of the expression is null. The input data in this case can be either the pressure in the tank or the outgoing mass flow. Heat exchange modeling is an important parameter of the model. In contrast to complex modelizations via Navier Stokes equations, thermal exchanges between the gas and the wall can be modeled via correlations based on dimensionless numbers. In the case of a high-pressure tank filling 200bar, 700bar or 1000bar, a correlation is recommended based on the numbers of Nusselt, Rayleigh and Prandtl NUDinty Rame and Rech.) For example according to the method described in the document EP2824378A1. The expression is for example: NuDint = a RaDintb + c Redind The Nusselt number (NuDint) is based on the internal diameter of the reservoir 15 and represents the convective heat exchanges between the gas and the wall. The correlation is based on two terms. A first term represents natural convection (based on the Rayleigh number) while the second term represents forced convection exchanges and depends on the Reynolds number. The coefficients a, b, c 'and d of correlation are assumed to be constant and depend solely on the geometry of the reservoir and the nature of the gas flow within it. This model can determine this expression (and therefore the coefficients) by tests. They are therefore known and frozen for different filling conditions.
    [0014] In the case of withdrawal the expression may be NUDint = a Rgnint. That is, the heat exchanges are due solely to the natural convection based on the Rayleigh number. This type of correlation is well known in the literature.
    [0015] 3036159 21 When wind blows around the tank, external heat exchanges between the tank and its environment can be modeled with a forced convection equation between air and a cylinder according to a formula such as: kaDext 0,5 2 Nua = = ((O.
    [0016] 4 Reije, + O.
    [0017] 06 Re) airl14) A-air Dext 5 If the wind is zero the Reynolds number can be considered zero. It is possible to choose a free convection correlation. Gas modeling, heat exchanges between the gas and the wall have thus been explained, the principle of the model calculating the evolution of the temperature of the wall will now be described.
    [0018] To solve the heat equation in the wall, the wall will be modeled in one dimension. A heat balance is carried out in an elementary volume element dV between the portions of radius r and r + dr (relative to the longitudinal axis of the tank). This elementary volume is a closed cylinder assumed to be homogeneous in temperature (T (r, t)). This elementary volume has a homogeneous thickness dr and an internal diameter r. its internal length is Lint + 2 (r - rint) with Lint and have respectively the internal length and the radius of a cylinder equivalent to zero dimension ("OD").
    [0019] The heat exchanges with the elementary volume and through a heat flow jr can be expressed according to the Fourier law j = -A gradT (r, t). The heat balance in the elemental volume can be expressed as follows: OT a-8T pcpdV -à7 = -i1r Or 1 Sr + 2i-r + dr nr r + ci I Sr + drr ur 25 At the interface between the gas and the inner wall (liner) we consider a continuity of power at time t + hit. Therefore: 3036159 22 P = kg (t Lit) Aint (7 'gcts (t + - T (run + bed)) = -2- (runer, t + At) gradT dA Aint OT = -2. (Runer , t + Lit) -dr dA A int At the interface between the composite and the liner we consider a flow equality (index "w" for flow in one direction, for example west, and index "e" for the opposite direction) t + At) (-0T) = -2 (re, t + At) HaT) 5 Or w ar e We consider a single temperature point for this interface between the composite and the liner expressed by T ( rLC, t). At the level of the interface with the environment we have the expression: t + At) (-ai) ka (t + At) (T (Of t, t + At) - Tamb) ECT (nD ext, t The term "left" represents the flow in the reservoir while the term "right" is the flow outside the reservoir at the surface of the reservoir. The discretization of one-dimensional wall equations has been described previously with the zero dimension discretization of the gas mass and the energy balance. In addition, the previously described correlation of the heat fluxes with the wall makes it possible to determine (calculate) the values of the average temperature of the gas as a function of time Tgas, average (t) and average temperature of the wall of the tank Twall, average ( r, t). From there, the device must determine the maximum temperature of the wall Twall, max (t).
    [0020] For this, the method uses a correlation between the mean wall temperature of the Twall tank, average (r, t) and the maximum wall temperature Twall, max (t). The temperature heterogeneities in the tank and the wall are considered to depend essentially on gas flow rates and velocities. A possible correlation has the following form: LD ..) Tweil, max (0 = f (Twall, average (linear, t), T gas, average (0, -D, - d, m 3036159 23 to determine this correlation (function f) of the experiments (fills, withdrawals) can be carried out by measuring the gas temperatures and the temperatures obtained at the level of the wall, simulations with two or three dimensions can make it possible to calculate the hot / cold spots 5 during filling / withdrawal From experimental measurements it has been observed that the Richardson number is very useful for determining the conditions of homogeneity or heterogeneity of the temperature in the reservoir The number of Richardson is given by Gr 10 Ri = Re2 Gr = v2 With g The Reynolds number can be written in the following way: P inv indin Redira = m With wine = 4 Ilitdrn Pfiv bottomp int 15 Or else ReDint = Fig With d inV in vbottom = 6, 2 X , I "int efté-expression is dependent on the tem ps t and can be calculated at each step by the model. The calculated Richardson number can be compared to a reference value Vr. This indicates the level of homogeneity during the filling / racking process. For tanks of cylindrical general shape with an L / D ratio (length L over diameter D) of less than 4.5 (L / D <4.5), the reference value can be of the order of 1. Ri < 1 indicates conditions of homogeneity and Ri> 1 indicates non-homogeneous conditions. During the gas transfer the transfer conditions can be adapted to maintain the homogeneity conditions. Under these conditions of homogeneity, the maximum temperature reached by the wall of the tank Twall, max (t) is the average temperature of the wall in contact with the gas.
    [0021] In this case, no correlation is required between the mean wall temperature in contact with the gas and the maximum wall temperature. For tanks in which the L / D ratio> 4.5 the heterogeneity conditions can be considered always present. In this case, a correlation is necessary.
    [0022] This method (calculation) can be applied during gas transfer in a filling / withdrawal station. Of course, these calculations can be made a priori for each type of tank to pre-establish the optimal conditions of gas transfer. Simulations may in particular be made to determine different filling rates and the temperature profiles obtained. In this way, it is possible to determine the optimal filling conditions beforehand (speed, flow, cooling). The invention applies both to the filling to control the heating of the tank and withdrawal to control the cooling of the tank.
    [0023] 3036159 25 Nomenclature and terms used surface (m2) A a Thermal conductivity (m2.s-1) cp Constant pressure gas mass heat (J.kg-1.K1) cv Constant volume gas heat mass (J .kg-1.K1) Diameter of the gas injector in the tank (m) ci D Diameter of the tank (m) Thickness (m) g Acceleration due to gravity (ms-2) h Specific enthalpy (J.kg -1) Heat exchange coefficient (Wm-2.K-1) L Tank length (m) m Mass in the tank (kg) Mass flow in the tank (also 'Q') (kg.s-1 ) M Molar mass of the gas used (kg.mo1-1) P Gas pressure (Pa) Po Atmospheric pressure (Pa) Heat flow (Js-1.m-2) r Radius, coordinated in the tank wall from of the longitudinal axis (m) R Perfect gas constant (J.mo1-1.K-1) S Tank surface (m2) t Time (s) T Temperature (K) Tfe Air temperature in contact with the outer wall of the tank (K) Tfi Temperature of the gas in contact with the inner wall of the tank (K) Twe Temperature of the wall in contact with the air (K) Tw, Temperature of the wall in contact with the gas (K) / Volume of the tank (m3) Volume molar (m3.mo1 -1) V Specific volume (m3.kg-1) Z Compressibility factor of the gas used in the real gas equation (dimensionless) Coefficient of thermal expansion (K1) Y Heat ratio r / r Emissivity of the gas external surface of the reservoir (dimensionless) A Thermal conductivity (Wm-1.K-1) p Dynamic viscosity (Pa. $) Joule-Thomson coefficient of the gas (K.Pa-1) p 1-4JT Density (kg.m -3) Gas velocity (ms -1) 3036159 26 Significance of air indices Ambient air Amb ambient composite property External wall f Final g Gas in Property or nature at the tank inlet int Internal liner Property of the inner shell (liner) of the reservoir 0 Initial w Property of the wall Parameter without dimension Nug Number of Nusselt of the gas, Nug = koint Nl iair RaDint 5 RaDext RedIn RaDext 10 Prair kaDext Number of air Nusselt, Nuair =, air Number of Rayleigh of the gas Number of Rayleigh of the ambient Reynolds number of the flux Reynolds number of the air Number of Prandtl of the air air, Prair gair cpair
    权利要求:
    Claims (15)
    [0001]
    REVENDICATIONS1. Method for filling or withdrawing a tank (1) of gas under pressure, in particular of fuel such as hydrogen gas, the tank being delimited by a wall of generally cylindrical shape having determined thermo-physical dimensions and properties and known, the method comprising a regulation of the flow rate of the gas introduced or, respectively of the withdrawn gas, and / or the temperature of said introduced gas, to prevent the tank from reaching a determined high temperature threshold or a low threshold determined temperature, the method being characterized in that it comprises a step of estimation in real time by calculation of at least one tank temperature among: the average temperature of the tank wall Twall, average (r, t) as a function of time (t), the maximum temperature reached by the Twall tank wall, max (t) as a function of time, the minimum temperature reached by the wall of the Twall tank, m in (t) as a function of time and in that the regulation of the flow rate of the gas flow or the temperature of the said gas is carried out as a function of the said calculated reservoir temperature.
    [0002]
    2. Method according to claim 1, characterized in that, during a filling, when the temperature of the reservoir (1) calculated reaches a high threshold (SH) determined, the flow and in particular the gas flow is decreased and / or the temperature of the gas supplied to the tank (1) is reduced by heat exchange with a source of cold.
    [0003]
    3. Method according to claim 1 or 2, characterized in that, during a filling, when the calculated reservoir temperature is below the high threshold (SH) of a determined value, the flow of gas and in particular its flow is increased and / or the temperature of said gas and / or tank is increased by heat exchange with a heat source.
    [0004]
    4. Method according to any one of claims 1 to 3 characterized in that it comprises a step of calculating the Richardson Number (Ri) for the gas in the tank (1) as a function of time, a step of comparing the number of Richardson number (Ri) calculated with a determined reference value (Vr) of between 0.05 and 1.5 and preferably between 0.05 and 0.15 and, when a number of Richardson number (Ri ) calculated is less than reference value (Vr) determined the temperature of the gas in the tank (1) is considered homogeneous, that is to say that the maximum temperature reached by the tank wall Twall, max (t) in function time 5 is equal to the average temperature of the wall of the Twall tank, average (r, t) in contact with the gas as a function of time (t): Twall, max (t) - = Twall, average (r = r_liner, t).
    [0005]
    5. Method according to claim 4, characterized in that when the number of calculated Richardson number (R1) is greater than the determined reference value (Vr), the temperature of the gas in the reservoir (1) is considered heterogeneous. that is, the maximum temperature reached by the wall of the Twall tank, max (t) as a function of time is not equal to the average temperature of the tank wall in contact with the gas as a function of time (t ) ie at the level of what forms the reservoir liner, Twall, average (r = reservoir liner radius, t), and under these conditions, the process involves a step of increasing the gas flow rate supplied to the reservoir (1) to reduce the value of Richardson number (Ri) calculated below the reference value (Vr) determined and thus make the gas homogeneous in temperature. 20
    [0006]
    6. Method according to claim 4 or 5, characterized in that, during a filling, when the Richardson Number (Ri) is greater than the reference value (Vr), the gas flow and in particular its flow is increased. .
    [0007]
    7. Method according to any one of claims 4 to 6, characterized in that it comprises, before filling or, respectively, before withdrawal, a step of determination or detection by sensor (s), the initial temperature T (0) gas in the tank (1), the initial pressure P (0) of the gas in the tank (1), the initial average temperature of the tank wall Tw, average (0) and a determination step of the initial gas mass in the reservoir m (0) and, when filling 30 when the number of calculated Richardson number (Ri) is lower than the reference value (Vr) determined, the temperature of the gas in the reservoir ( 1) is considered homogeneous, that is to say that the maximum temperature reached by the wall of the Twall tank, max (t) as a function of time is equal to the average temperature of the wall of the tank Twall, average ( r = r = radius of the liner of the tank, t) in contact with the gas depending on the time (t), and under these conditions, the method comprises, during filling, a step of calculating the average temperature Tgas, average (t) of the gas in the tank (1) in real time as a function of time and the average temperature of the wall Twall, average (r, t) in real time as a function of time (t) from a mass and enthalpy balance applied to the gas in the tank (1) and also from an energy balance in the tank wall, the gas state equation (in particular the equation of the real gases), and a balance 10 of the heat exchange between the gas and the wall, and between the wall the tank is outside.
    [0008]
    8. Method according to any one of claims 4 to 7, characterized in that it comprises, before filling or, respectively, before withdrawal, a step of determination or detection by sensor (s), 15 of the initial temperature T (0) gas in the tank (1), the initial pressure P (0) of the gas in the tank (1), the initial average temperature of the tank wall Tw, average (0) and a determination step of the initial mass of gas in the tank m (0) and, during a filling when the number of Richardson number (Ri) calculated is greater than 20 reference value (Vr) determined the temperature of the gas in the tank ( 1) is considered heterogeneous, that is to say that the maximum temperature reached by the Twall tank wall, max (t) as a function of time is not equal to the mean temperature of the wall of the tank Twall, average ( r) = r_liner, t) in contact with the gas as a function of time (t), and 25 in this Under conditions, the process includes, during filling, a step of calculating the temperature Tgas, average (t) of the gas in the tank (1) in real time as a function of time (t) and the average temperature of the gas. the Twall wall, average (r, t) in real time as a function of time from a mass and enthalpy balance applied to the gas in the tank 30 (1) and an energy balance in the wall of the reservoir, of the equation of state of the gas (equation of the perfect or real gases), and of a balance of the thermal exchanges between the wall of the reservoir is the outside and in that the method comprises a step of calculation of the maximum temperature reached by the wall of the Twall tank, max (t) as a function of time, this maximum temperature reached by the wall of the Twall tank, max (t) as a function of time being obtained by correlation from the temperature Tgas, average (t) of the gas in the tank (1) calculated in real time ction of the time and as a function of the average temperature of the Twall wall, average (r, t) in real time as a function of time (t).
    [0009]
    9. The method of claim 7 or 8, characterized in that it comprises a step of calculating the enthalpy hin (t) of the gas entering or leaving the tank (1) as a function of time, a measurement step or calculating the mass of gas m (t) introduced or withdrawn from the tank as a function of time or, respectively, a step of determining the pressure P (t) in the tank (1) as a function of time, the method comprising a step of determining the average temperature of the gas Tgas, average (t) at the instant t in the tank (1) in degree K, this average temperature Tgas, average (t) being expressed as a function of the first degree of the average temperature of the gas T (t-1) at the previous instant (t-1) and a convective heat exchange coefficient between the gas and the inner wall of the tank (1) at the instant (t-1) ) in W.rn2.K-1, in which the heat exchange coefficient kg (t-1) is given by the relation kg = (Ag / Dint) .Nuint in which Ag is the thermal conductivity of the gas in the tank in Wm-1.1 <-1, Dint is the internal diameter of the tank (1) in meter and NuDint the number of Nusselt of the gas in the tank (1) (dimensionless), and in where the Nusselt number of the gas is expressed as a function of the Reynolds number (Redin) (dimensionless) relative to the forced convection in the reservoir (1) and the Rayleigh number (RaDint) (dimensionless) relative to the convection internal natural in the tank (1) according to a formula NuDint = a.RaDintb + c.Redind in which a and c are dimensionless coefficients depending on the ratio (Lint / Dint) between the internal length of the tank Lint in meter and the diameter the reservoir Dint in meters and the ratio (Dint / di) between the internal diameter of the reservoir Dint in meters and the diameter of the injector di in meters, a, b, c and d being dimensionless positive real numbers, a being between 0 and 1, b being between 0.2 and 0, 5, c being between 0 and 1 and d being between 0.5 and 0.9. 303 6 15 9 31
    [0010]
    10.Procédé according to any one of claims 7 to 9, characterized in that it comprises a step of estimating the maximum temperature reached in the thickness of the tank Twall, max (t) as a function of time, respectively the minimum temperature reached in the thickness of the Twall tank, min (t) as a function of time, from the temperature Tgas, average (t) average of the gas in the tank (1) calculated in real time as a function of time (t), said maximum or minimum temperature being obtained from correspondence table (s) obtained by experiments, and / or from calculation and / or simulations so that at a Tgas temperature, average (t) of the gas in the tank (1) calculated in real time as a function of time (t) corresponds, according to the known conditions of gas flow, the gas injector diameter in the tank and the dimensions and characteristics of the tank (1), a maximum temperature or, respectively minimum, in the thickness of the tank as a function of time.
    [0011]
    11.Procédé according to any one of claims 4 to 9, characterized in that the Richardson Number (Ri) for the gas in the tank (1) as a function of time is calculated from the number of Grashoff (Gr) for the gas and the Reynolds number (Re) for the gas at time (t) according to the following formula: Ri = Gr / Re2, in which the Grashof (Gr) and Reynolds (Re) numbers are known data or calculated from the pressure value of the measured gas or gas mass in the tank and the gas temperature Tgas, average (t) of the gas in the tank (1). 25
    [0012]
    12.Procédé according to any one of claims 1 to 10, characterized in that, during a withdrawal, when the calculated tank temperature reaches a determined low threshold (SB), the gas flow is decreased.
    [0013]
    13.Procédé according to any one of claims 1 to 12, characterized in that it comprises a step of continuously measuring or calculating at least one of: the pressure Pin (t) at time (t) the gas introduced into or withdrawn from the tank, the temperature Tin (t) at the time (t) of the gas introduced into or withdrawn from the tank, the P (t) pressure in the tank 3036159 32 at the time (t), the ambient temperature ( Tamb (t) at time (t), gas mass m (t) in tank (1) at time (t).
    [0014]
    14. Method according to any one of claims 1 to 13, characterized in that it is implemented by a filling station of 5 hydrogen gas tanks comprising at least one source (10) of hydrogen at high pressure, at least one gas transfer line (2) selectively connecting the source (1) to a reservoir (1), and an electronic data acquisition, storage and processing member (4) such as a computer or microprocessor , said member (4) controlling the transfer of gas between the source (10) and the reservoir (1), characterized in that the logic (4) is programmed to calculate in real time at least one temperature of the reservoir (1 ) from: the average temperature of the tank wall Twall, average (r, t) as a function of time (t), the maximum temperature reached in the thickness of the tank Twall, max (t) as a function of time, the minimum temperature reached in the thickness of the Twall tank, min (t) in f time and to regulate the flow rate of the gas flow and / or the temperature of said gas as a function of said calculated reservoir temperature.
    [0015]
    15.Device for filling or withdrawing gas from a tank (1) comprising a line (2) for transfer comprising a valve (3) and connectable to a tank (1), the device comprising an electronic member (4) for acquiring, storing and processing data, such as a computer or microprocessor, said member (4) controlling the transfer of gas between the source (10) and the reservoir (1), characterized in that the logic (4 The electronic circuit is programmed to calculate at least one temperature of the reservoir (1) from: the average temperature of the wall of the Twall tank, average (r, t) according to its thickness (radius r) and as a function of time (t), the maximum temperature reached in the thickness of the Twall tank, max (t) as a function of time, the minimum temperature reached in the thickness of the Twall tank, min (t) as a function of time and to regulate the flow rate of the flow of gas as a function of said calculated current tank temperature.
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    同族专利:
    公开号 | 公开日
    US20180112828A1|2018-04-26|
    FR3036159B1|2017-05-05|
    WO2016181057A1|2016-11-17|
    US10704737B2|2020-07-07|
    EP3295074B1|2020-01-08|
    EP3295074A1|2018-03-21|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    FR2884592A1|2005-04-13|2006-10-20|Air Liquide|METHOD FOR CONTROLLING THE FILLING OF GAS BOTTLES|
    US20140290790A1|2010-04-21|2014-10-02|Honda Motor Co., Ltd.|Method and system for tank refilling using active fueling speed control|
    WO2013014346A1|2011-07-22|2013-01-31|L'air Liquide,Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude|Method for filling a tank with pressurised gas|
    EP2824378A1|2013-07-10|2015-01-14|L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude|Method for filling a gas tank|
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    FR3057644B1|2016-10-19|2018-10-19|L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude|METHOD AND DEVICE FOR FILLING A PRESSURE GAS TANK|
    DE102018121267A1|2018-08-31|2020-03-05|Bayerische Motoren Werke Aktiengesellschaft|Method for operating a motor vehicle and motor vehicle|
    CN109654372A|2018-12-05|2019-04-19|潍柴动力股份有限公司|A kind of control method and device of hydrogen storage equipment|
    法律状态:
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    2016-11-18| PLSC| Publication of the preliminary search report|Effective date: 20161118 |
    2017-05-23| PLFP| Fee payment|Year of fee payment: 3 |
    2018-05-22| PLFP| Fee payment|Year of fee payment: 4 |
    2019-05-22| PLFP| Fee payment|Year of fee payment: 5 |
    2020-05-22| PLFP| Fee payment|Year of fee payment: 6 |
    2022-02-11| ST| Notification of lapse|Effective date: 20220105 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1554207A|FR3036159B1|2015-05-12|2015-05-12|METHOD AND DEVICE FOR FILLING OR STUCKING A PRESSURE GAS TANK|FR1554207A| FR3036159B1|2015-05-12|2015-05-12|METHOD AND DEVICE FOR FILLING OR STUCKING A PRESSURE GAS TANK|
    EP16726131.2A| EP3295074B1|2015-05-12|2016-05-04|Method and device for filling or withdrawing from a pressurized gas tank|
    US15/573,246| US10704737B2|2015-05-12|2016-05-04|Method and device for filling or withdrawing from a pressurized gas tank|
    PCT/FR2016/051063| WO2016181057A1|2015-05-12|2016-05-04|Method and device for filling or withdrawing from a pressurized gas tank|
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